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Enzyme@bismuth-ellagic acid: a versatile platform for enzyme immobilization with enhanced acid-base stability

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 6,   Pages 784-794 doi: 10.1007/s11705-022-2278-4

Abstract: In situ encapsulation is an effective way to synthesize enzyme@metal–organic framework biocatalystsAfter encapsulation, the stability, especially the acid-base stability, of amyloglucosidases@bismuth-ellagicgreen precursor, simple and convenient preparation process provided a versatile strategy for enzymes encapsulation

Keywords： bismuth-ellagic acid     in situ encapsulation     enzyme@MOF biocomposites    

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Development and application of ex-situ presulfurization technology for hydrotreating catalysts in China

Yulan GAO, Xiangchen FANG, Zhenmin CHENG

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 3,   Pages 287-296 doi: 10.1007/s11705-010-0529-2

Abstract: The development and application of ex-situ presulfurization (EPRES) technology for hydrotreating catalysts

Keywords： ex-situ presulfurization     in situ presulfurization     hydrotreating catalyst     sulfur utilization ratio    

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Polyolefin-nanocomposites with special properties by in-situ polymerization

Walter Kaminsky

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 3,   Pages 555-563 doi: 10.1007/s11705-018-1715-x

Abstract:

Exceptionally strong polyolefin nanocomposites are synthesized by in-situ polymerization using

Keywords： polyolefin nanocomposites     metallocenes     methylaluminoxane    

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The effects of mismatch fracture properties in encapsulation-based self-healing concrete using cohesive-zone

Luthfi Muhammad MAULUDIN, Chahmi OUCIF, Timon RABCZUK

Frontiers of Structural and Civil Engineering 2020, Volume 14, Issue 3,   Pages 792-801 doi: 10.1007/s11709-020-0629-0

Abstract: Finite element analysis is developed to simulate the breakage of capsule in capsule-based self-healing concrete. A 2D circular capsule with different core-shell thickness ratios embedded in the mortar matrix is analyzed numerically along with their interfacial transition zone. Zero-thickness cohesive elements are pre-inserted into solid elements to represent potential cracks. This study focuses on the effects of mismatch fracture properties, namely fracture strength and energy, between capsule and mortar matrix into the breakage likelihood of the capsule. The extensive simulations of 2D specimens under uniaxial tension were carried out to investigate the key features on the fracture patterns of the capsule and produce the fracture maps as the results. The developed fracture maps of capsules present a simple but valuable tool to assist the experimentalists in designing appropriate capsule materials for self-healing concrete.

Keywords： self-healing concrete     interfacial zone     capsule materials     cohesive elements     fracture maps    

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Immobilization of

Xiaokai SONG,Zhongyi JIANG,Lin LI,Hong WU

Frontiers of Chemical Science and Engineering 2014, Volume 8, Issue 3,   Pages 353-361 doi: 10.1007/s11705-014-1421-2

Abstract: Mesoporous silica particles were prepared for efficient immobilization of the -glucuronidase (GUS) through a biomimetic mineralization process, in which the solution containing lysozyme and GUS were added into the prehydrolyzed tetraethoxysilane (TEOS) solution. The silica particles were formed in a way of biomineralization under the catalysis of lysozyme and GUS was immobilized into the silica particles simultaneously during the precipitation process. The average diameter of the silica particles is about 200 nm with a pore size of about 4 nm. All the enzyme molecules are tightly entrapped inside the biosilica nanoparticles without any leaching even under a high ionic strength condition. The immobilized GUS exhibits significantly higher thermal and pH stability as well as the storage and recycling stability compared with GUS in free form. No loss in the enzyme activity of the immobilized GUS was found after 30-day’s storage, and the initial activity could be well retained after 12 repeated cycles.

Keywords： and recycling stability     silica nanoparticles     biocatalysis     biomimetic synthesis     β-glucuronidase encapsulation    

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Propagation characteristics of transient waves in low-strain integrity testing on cast-in-situ concrete

Hanlong LIU, Xuanming DING

Frontiers of Structural and Civil Engineering 2009, Volume 3, Issue 2,   Pages 240-240 doi: 10.1007/s11709-009-0100-8

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Thermodynamic analysis of liquid phase in situ hydrogenation of glycerol for 1,3-propanediol synthesis

Kun OUYANG, Yu HUANG, Haoyi CHEN, Tao LI, Fahai CAO, Dingye FANG

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 1,   Pages 67-73 doi: 10.1007/s11705-010-0541-6

Abstract: reforming (APR) and catalytic hydrogenation of glycerol, a novel reaction system of liquid phase in situreforming reaction; the hydrogen generated from the APR of glycerol can be quickly transformed to the in situ

Keywords： glycerol     aqueous-phase reforming     1     3-propanediol     in-situ reduction    

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In situ-based assessment of soil liquefaction potential–Case study of an earth dam in Tunisia

Ikram GUETTAYA,Mohamed Ridha EL OUNI

Frontiers of Structural and Civil Engineering 2014, Volume 8, Issue 4,   Pages 456-461 doi: 10.1007/s11709-014-0259-5

Abstract: The present paper examines the evaluation of liquefaction potential of an earth dam foundation in Tunisia. The assessment of soil liquefaction was made using deterministic and probabilistic simplified procedures developed from several case histories. The data collected from the field investigation performed before and after the vibrocompaction are analyzed and the results are reported. The obtained results show that after vibrocompaction, a significant improvement of the soil resistance reduces the liquefaction potential of the sandy foundation. Indeed, in the untreated layers, the factor of safety drops below 1 which means that the soil is susceptible for liquefaction. However, in the compacted horizons, the values of exceed the unit which justifies the absence of liquefaction hazard of the foundation.

Keywords： liquefaction     cone penetration test (CPT)     standard penetration test (SPT)     vibrcompaction     sand    

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In situ synthesis of FeS/Carbon fibers for the effective removal of Cr(VI) in aqueous solution

Rongrong Zhang, Daohao Li, Jin Sun, Yuqian Cui, Yuanyuan Sun

Frontiers of Environmental Science & Engineering 2020, Volume 14, Issue 4, doi: 10.1007/s11783-020-1247-8

Abstract: Abstract • FeS/carbon fibers were in situ synthesized with Fe-carrageenan hydrogel fiber. • The doubleTherefore, this study investigates in situ synthesized FeS/carbon fibers with an Fe-carrageenan biomass

Keywords： Carrageenan     FeS     Double-helix structure     Hexavalent chromium    

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In-situ condition monitoring of reinforced concrete structures

Sanjeev Kumar VERMA,Sudhir Singh BHADAURIA,Saleem AKHTAR

Frontiers of Structural and Civil Engineering 2016, Volume 10, Issue 4,   Pages 420-437 doi: 10.1007/s11709-016-0336-z

Abstract: deterioration mechanisms, performance characteristics and parameters and condition monitoring of in situ

Keywords： concrete     carbonation     chloride     corrosion     monitoring     models    

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Encapsulation of polyethylene glycol in cellulose-based porous capsules for latent heat storage and light-to-thermal

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 8,   Pages 1038-1050 doi: 10.1007/s11705-022-2279-3

Abstract: Phase change materials are potential candidates for the application of latent heat storage. Herein, we fabricated porous capsules as shape-stable materials from cellulose-based polyelectrolyte complex, which were first prepared using cellulose 6-(N-pyridinium)hexanoyl ester as the cationic polyelectrolyte and carboxymethyl cellulose as the anionic polyelectrolyte to encapsulate polyethylene glycol by the vacuum impregnation method. Furthermore, the multi-walled carbon nanotube or graphene oxide, which were separately composited into the polyelectrolytes complex capsules to enhance thermal conductivity and light-to-thermal conversion efficiency. These capsules owned a typical core–shell structure, with an extremely high polyethylene glycol loading up to 34.33 g∙g‒1. After loading of polyethylene glycol, the resulted cellulose-based composite phase change materials exhibited high thermal energy storage ability with the latent heat up to 142.2 J∙g‒1, which was 98.5% of pure polyethylene glycol. Further results showed that the composite phase change materials demonstrated good form-stable property and thermal stability. Moreover, studies involving light-to-thermal conversion determined that composite phase change materials exhibited outstanding light-to-thermal conversion performance. Considering their exceptional comprehensive features, innovative composite phase change materials generated from cellulose presented a highly interesting choice for thermal management and renewable thermal energy storage.

Keywords： cellulose     polyelectrolytes     phase change materials     thermal energy storage     light-to-thermal conversion    

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Phase problems in optical imaging Review

Guo-hai SITU, Hai-chao WANG

Frontiers of Information Technology & Electronic Engineering 2017, Volume 18, Issue 9,   Pages 1277-1287 doi: 10.1631/FITEE.1700298

Abstract: Because the phase contains more information about the fieldcompared to the amplitude, measurement of the phase is encounteredin many branches of modern science and engineering. Direct measurementof the phase is difficult in the visible regime of the electromagneticwave. One must employ computational techniques to calculate the phasefrom the captured intensity. In this paper, we provide a review ofour recent work on iterative phase retrieval techniques and theirapplications in optical imaging.

Keywords： Phase retrieval     Phase imaging     Computational imaging     Gerchberg-Saxton algorithm     Optical encryption     Computer-generated hologram    

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In situ enhanced bioremediation of dichlorvos by a phyllosphere

Jiying NING, Gang GANG, Zhihui BAI, Qing HU, Hongyan QI, Anzhou MA, Xuliang ZHUAN, Guoqiang ZHUANG

Frontiers of Environmental Science & Engineering 2012, Volume 6, Issue 2,   Pages 231-237 doi: 10.1007/s11783-011-0316-4

Abstract: A bacterium capable of degrading dichlorvos was isolated from the rape phyllosphere and designated YD4. The strain was identified as sp., based on its phenotypic features and 16S rRNA gene sequence. Strain YD4 was able to utilize dichlorvos as the sole source of phosphorus. enhanced bioremediation of dichlorvos by YD4 was hereafter studied. Chlorpyrifos and phoxim could also be degraded by this strain as the sole phosphorus source. A higher degradation rate of dichlorvos was observed after spraying YD4 onto the surface of rape leaves when compared to the sterilized-YD4 and water-treated samples. The results indicated that pesticide-degrading epiphytic bacterium could become a new way for phyllosphere bioremediation where the hostile niche is unsuitable for other pesticide-degrading bacteria isolated from soil and water.

Keywords： enhanced bioremediation     organophosphorus pesticides     phyllosphere     Flavobacterium sp.    

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Investigate of in situ sludge reduction in sequencing batch biofilm reactor: Performances, mechanisms

Yonglei Wang, Baozhen Liu, Kefeng Zhang, Yongjian Liu, Xuexin Xu, Junqi Jia

Frontiers of Environmental Science & Engineering 2018, Volume 12, Issue 5, doi: 10.1007/s11783-018-1077-0

Abstract: listitem>

Microbial metabolism uncoupling, sludge decay is the main mechanism to promote in situ

Keywords： In situ sludge reduction     Biofilm     Composite floating spherical carriers     Microbial community     SBBR    

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Development of an H reduction and moderate oxidation method for 3,5-dimethylpyridine hydrogenation in trickle bed reactor

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 12,   Pages 1807-1817 doi: 10.1007/s11705-022-2243-2

Abstract: Under the same reduction conditions (300 °C in H2), the catalytic activity of the non-in-situ reduced Ru/C-n catalyst was higher than that of the in-situ reduced Ru/C-y catalyst.Therefore, an in-situ H2 reduction and moderate oxidation method was developed to increaseThe developed in-situ H2 reduction and moderate oxidation method eliminated the stepof the non-in-situ reduction of catalyst outside the trickle bed reactor.

Keywords： Ru/C catalyst     in-situ H2 reduction and moderate oxidation     in-situ reduction     non-in-situ reduction     hydrogenation of 3     5-dimethylpyridine    

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Title Author Date Type Operation

Enzyme@bismuth-ellagic acid: a versatile platform for enzyme immobilization with enhanced acid-base stability

Journal Article

Development and application of ex-situ presulfurization technology for hydrotreating catalysts in China

Yulan GAO, Xiangchen FANG, Zhenmin CHENG

Journal Article

Polyolefin-nanocomposites with special properties by in-situ polymerization

Walter Kaminsky

Journal Article

The effects of mismatch fracture properties in encapsulation-based self-healing concrete using cohesive-zone

Luthfi Muhammad MAULUDIN, Chahmi OUCIF, Timon RABCZUK

Journal Article

Immobilization of

Xiaokai SONG,Zhongyi JIANG,Lin LI,Hong WU

Journal Article

Propagation characteristics of transient waves in low-strain integrity testing on cast-in-situ concrete

Hanlong LIU, Xuanming DING

Journal Article

Thermodynamic analysis of liquid phase in situ hydrogenation of glycerol for 1,3-propanediol synthesis

Kun OUYANG, Yu HUANG, Haoyi CHEN, Tao LI, Fahai CAO, Dingye FANG

Journal Article

In situ-based assessment of soil liquefaction potential–Case study of an earth dam in Tunisia

Ikram GUETTAYA,Mohamed Ridha EL OUNI

Journal Article

In situ synthesis of FeS/Carbon fibers for the effective removal of Cr(VI) in aqueous solution

Rongrong Zhang, Daohao Li, Jin Sun, Yuqian Cui, Yuanyuan Sun

Journal Article

In-situ condition monitoring of reinforced concrete structures

Sanjeev Kumar VERMA,Sudhir Singh BHADAURIA,Saleem AKHTAR

Journal Article

Encapsulation of polyethylene glycol in cellulose-based porous capsules for latent heat storage and light-to-thermal

Journal Article

Phase problems in optical imaging

Guo-hai SITU, Hai-chao WANG

Journal Article

In situ enhanced bioremediation of dichlorvos by a phyllosphere

Jiying NING, Gang GANG, Zhihui BAI, Qing HU, Hongyan QI, Anzhou MA, Xuliang ZHUAN, Guoqiang ZHUANG

Journal Article

Investigate of in situ sludge reduction in sequencing batch biofilm reactor: Performances, mechanisms

Yonglei Wang, Baozhen Liu, Kefeng Zhang, Yongjian Liu, Xuexin Xu, Junqi Jia

Journal Article

Development of an H reduction and moderate oxidation method for 3,5-dimethylpyridine hydrogenation in trickle bed reactor

Journal Article